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How Copper Sprays Work and Avoiding Phytotoxicity

June 26, 2013

How Copper Sprays Work and Avoiding Phytotoxicity
Copper has been widely used in both conventional and organic production for some time. Copper was one of the first elements used as a plant fungicide (the other was Sulfur). Its discovery can be traced back to the famous origin of Bordeaux mixture, containing a mixture of copper sulfate (CuSO4) and slaked lime, and used for downy mildew control in French vineyards.

Recently, growers have asked me questions regarding the mode of action of copper and had  concerns about phytotoxicity. First, let's begin with how copper controls pathogens. Copper is usually applied in the fixed form which lowers its solubility in water. Fixed coppers include basic copper sulfate (e.g., Cuprofix Ultra Disperss), copper oxide (e.g., Nordox), copper hydroxide (e.g., Kocide, Champ), copper oxychloride sulfate (e.g., COCS), and copper ions linked to fatty acids or other organic molecules (e.g., TennCop, Cueva). The spray solution is actually a suspension of copper particles, and those particles persist on plant surfaces after the spray dries. Copper ions are gradually released from these copper deposits each time the plant surface becomes wet. The gradual release of copper ions from the copper deposits provides residual protection against plant pathogens. At the same time, the slow release of copper ions from these relatively insoluble copper deposits reduces risks of phytotoxicity to plant tissues. Copper ions denature proteins, thereby destroying enzymes that are critical for cell functioning. Copper can kill pathogen cells on plant surfaces, but once a pathogen enters host tissue, it will no longer be susceptible to copper treatments. Thus, copper sprays act as protectant fungicide/bactericide treatments, but lack post-infection activity.

Because different formulations have different properties when used as spray materials, growers need to learn how to read and interpret labels. The effectiveness of copper sprays is highly correlated with the amount of elemental copper that is applied. The metallic copper content varies widely by product. Potency also varies by how the product is prepared. Finely ground copper products are more active than coarsely ground ones. Professor Tom Zitter of Cornell University suggests that for vegetable crops. Begin by choosing a copper product with at least 20% or more copper as the active ingredient to insure the greatest release of copper ions.

There are several suggestions for avoiding phytoxicity (or plant injury) with copper sprays. Limit the copper ion concentration on plant surfaces by using copper products that are relatively insoluble in water, i.e. fixed copper. Copper can accumulate to high levels on plant tissue when sprayed repeatedly to cover new growth and there is no rain. In this situation, after a rain event, a large amount of copper ions may be released leading to phytotoxicity. Solubility of fixed coppers increases under acidic conditions. Copper sprays will become more phytotoxic if they are applied in an acidic solution. Most copper products are formulated to be almost insoluble in water at pH 7.0. As the pH of water decreases the solubility of the copper fungicides increases and more copper ions are released. If the water used is too acidic (below pH 6.0-7.0 depending on the copper formulation) excessive amounts of copper ions could be produced which may cause damage to fruit and foliage. Formulations vary in solubility hydroxides are more soluble than oxychlorides which are more soluble than tribasic copper sulphates and cuprous. Less soluble formulations are usually more persistent. Check the pH of your water source. Copper sprays generally cause more phytotoxicity when applied under slow drying conditions, such as when it's wet and cool.  Always read the label instructions follow the Copper and tank mix partner labels.
For a comprehensive list of Copper Products Used for Vegetable Disease Control see
http://vegetablemdonline.ppath.cornell.edu/NewsArticles/CopperFungicides2012.pdf


Sources: T. A. Zitter, Cornell University Department of Plant Pathology & Plant-Micrbiology and David A. Rosenberger, Professor of Plant Pathology, Cornell University's Hudson Valley Lab


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Upcoming Events

Urban and Small-Scale Growers Meeting

April 5, 2024
Buffalo, NY

This event is an opportunity for small-scale growers, urban growers, community garden leaders and ag service providers to build community, engage in production-focused workshops, and share resources. Topics include building soil productivity, insect and disease management, growing vegetables, berries, and tree fruits, and more.

REGISTRATION IS CLOSED! We met the space limitation for this event.

View Urban and Small-Scale Growers Meeting Details

2024 DEC Special Permit Handler Training -- Wayne County

April 9, 2024
Newark, NY

Special Permits (SP) will relieve the certified pesticide applicator from "on-site within voice contact" supervision of non-certified pesticide applicators when they are handling federally-restricted-use pesticides for which they hold a Special Permit. The 8 specific labels covered: Endigo ZCX, Warrior II with Zeon Technology, Agri-Mek SC, Beseige, Leverage 360, Danitol 2.4EC, Mustang Maxx, and Lannate LV. 

View 2024 DEC Special Permit Handler Training -- Wayne County Details

2024 DEC Special Permit Handler Training -- Orleans County

April 10, 2024
Albion, NY

Special Permits (SP) will relieve the certified pesticide applicator from "on-site within voice contact" supervision of non-certified pesticide applicators when they are handling federally-restricted-use pesticides for which they hold a Special Permit. The 8 specific labels covered: Endigo ZCX, Warrior II with Zeon Technology, Agri-Mek SC, Beseige, Leverage 360, Danitol 2.4EC, Mustang Maxx, and Lannate LV. 

View 2024 DEC Special Permit Handler Training -- Orleans County Details

Announcements

JOB POSTING: Onion Crop Scout

Be a Vital Part of New York Onion Production!

We are looking for someone who appreciates agriculture to scout commercial onion fields in Oswego Co. and/or Wayne Co. for 13 weeks during the summer, maximum 19 hours/week, who would return to the seasonal position annually.

As an Onion Crop Scout for the Cornell Vegetable Program (CVP), you will independently scout 11 commercial onion fields collecting data on insect pests, diseases, weeds and crop stage/quality. Scouting data will be summarized into a preliminary report which is finalized by Cornell's Onion Specialist. Growers use the scouting reports to inform their spray decisions, which enables an integrated approach to pest management. Your hard work will ensure grower engagement, implementation of research-based recommendations, and early detection of emerging issues. It is the "beating heart" of CVP's onion program.

Pay: $18.50/hr. No benefits. Personal mileage will be reimbursed at the federal rate.

Key Qualifications & Skills:
  • High School diploma and 6 months experience in an agriculture setting, or the equivalent combination of education and experience.
  • Must be able to meet the travel requirements of the position and have reliable transportation as well as have and maintain a valid and unrestricted New York State driver's license.
  • Visual concentration and attention to detail are required to detect pests and pest damage.
  • Able to work independently in collecting and summarizing data.
  • Must be able to work outdoors in all types of weather.
  • Proven experience in communicating effectively, both written and oral.
  • Preferred: Experience working with plants, plant disease and other pest identification.
Training will include being accompanied by a veteran onion scout for the first season with the intention of scouting independently in the second year, and ideally for several more years after.

Flexible on start and end dates, day(s) of week you work, and whether Oswego or Wayne or both counties are scouted. Our priority is finding someone who will return to the position annually.

Read details about the Onion Crop Scout position.

To apply (resume and cover letter): http://tiny.cc/Onion_Scout_WDR_00043345

Management Practices for High Organic Matter Soils

We are exploring management practices for vegetable farmers with high organic matter soils. These soils are usually found in urban growing areas as urban farmers typically grow in imported soil mixtures that have been constructed over time and in high tunnels where leaching events are limited. In both cases, we see that soil pH and calcium levels can increase due to alkaline irrigation water and with grower inputs such as high levels of compost and/or fertilizer. We commonly see limited plant nutrient uptake due to high soil pH. We have produced four "Management Practices for Urban Soil Health" case studies sharing project updates in our urban cover crop, pH adjustment, and bulk density adjustment work. In each case study, we are looking at the effect of the management practice on soil and crop health. 

Management Practices for Urban Soil Health: Cover Cropping
Management Practices for Urban Soil Health: pH Adjustment
Management Practices for Urban Soil Health: pH Adjustment in NYC
Management Practices for Urban Soil Health: Correcting Nutrient Test Results for Soils with High Organic Matter

2023 Year in Review and 2024 Preview

As the Cornell Vegetable Program reflects on 2023, we want to thank you for your partnership and continued support of our team and the work we do to address issues impacting the commercial vegetable industry in the western and central portion of NYS. Our 2023 Year in Review and 2024 Preview report highlights of some of the many research and outreach programs led by our team members over the last year plus a look ahead to some of our plans for 2024.
  • Use of Ground Barriers as a New Strategy for Swede Midge in Brassicas for Small Organic and Urban Farms
  • Cornell Vegetable Program Responds to Late Blight in 2023
  • Working Groups Help to Improve the Western NY Food System
  • Field Trials Completed to Test Lasers as a Bird Deterrent in Sweet Corn
  • Increased Monitoring of Western Bean Cutworm in Dry Beans
  • Sweet Potato Varieties Suitable for Western NY Production?


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